上游原料
Formaldehyde; ParaformaldehydeDimethyl acetylenedicarboxylate; Dimethyl 2-butynedioate;Acetylenedicarboxylic acid dimethyl ester6-Bromo-1,3-benzodioxole-5-carbaldehyde dimethyl acetal; 5-Bromo-6-(dimethoxymethyl)-1,3-benzodioxole; (6-Bromo-1,3-benzodioxol-5-yl)(methoxy)methyl methyl ether6-(dimethoxymethyl)-1,3-benzodioxole-5-carbaldehyde[6-(dimethoxymethyl)-1,3-benzodioxol-5-yl]methanolfuro[3,4-f][1,3]benzodioxoledimethyl (1R,11S)-5,7,14-trioxatetracyclo[9.2.1.0(2,10).0(4,8)]tetradeca-2(10),3,8,12-tetraene-12,13-dicarboxylatedimethyl (1R,11S,12S,13R)-5,7,14-trioxatetracyclo[9.2.1.0(2,10).0(4,8)]tetradeca-2(10),3,8-triene-12,13-dicarboxylate[(1S,11R,12S,13R)-13-(hydroxymethyl)-5,7,14-trioxatetracyclo[9.2.1.0(2,10).0(4,8)]tetradeca-2(10),3,8-trien-12-yl]methanol[(1R,11S,12S,13R)-13-[(acetoxy)methyl]-5,7,14-trioxatetracyclo[9.2.1.0(2,10).0(4,8)]tetradeca-2(10),3,8-trien-12-yl]methyl acetate[(1S,11R,12S,13R)-13-(hydroxymethyl)-5,7,14-trioxatetracyclo[9.2.1.0(2,10).0(4,8)]tetradeca-2(10),3,8-trien-12-yl]methyl acetate[(1S,11R,12S,13R)-13-([[tert-butyl(dimethyl)silyl]oxy]methyl)-5,7,14-trioxatetracyclo[9.2.1.0(2,10).0(4,8)]tetradeca-2(10),3,8-trien-12-yl]methyl acetate[(1S,11R,12S,13R)-13-([[tert-butyl(dimethyl)silyl]oxy]methyl)-5,7,14-trioxatetracyclo[9.2.1.0(2,10).0(4,8)]tetradeca-2(10),3,8-trien-12-yl]methanol(1S,11R,12R,13R)-13-([[tert-butyl(dimethyl)silyl]oxy]methyl)-5,7,14-trioxatetracyclo[9.2.1.0(2,10).0(4,8)]tetradeca-2(10),3,8-triene-12-carbaldehyde(1S,11R,12R,13R)-13-[[(triisopropylsilyl)oxy]methyl]-5,7,14-trioxatetracyclo[9.2.1.0(2,10).0(4,8)]tetradeca-2(10),3,8-triene-12-carbaldehyde(7R,8R)-8-hydroxy-7-[[(triisopropylsilyl)oxy]methyl]-7,8-dihydronaphtho[2,3-d][1,3]dioxole-6-carbaldehyde(7R,8R)-7-[[(triisopropylsilyl)oxy]methyl]-8-[[2-(trimethylsilyl)ethoxy]methoxy]-7,8-dihydronaphtho[2,3-d][1,3]dioxole-6-carbaldehydeDimethylformamide1,3-oxazolidin-2-one(7R,8R)-7-[[(triisopropylsilyl)oxy]methyl]-8-[[2-(trimethylsilyl)ethoxy]methoxy]-7,8-dihydronaphtho[2,3-d][1,3]dioxole-6-carbaldehyde(7R,8R)-7-[[(triisopropylsilyl)oxy]methyl]-8-[[2-(trimethylsilyl)ethoxy]methoxy]-7,8-dihydronaphtho[2,3-d][1,3]dioxole-6-carboxylic acid3-[((7R,8R)-7-[[(triisopropylsilyl)oxy]methyl]-8-[[2-(trimethylsilyl)ethoxy]methoxy]-7,8-dihydronaphtho[2,3-d][1,3]dioxol-6-yl)carbonyl]-1,3-oxazolidin-2-onebromo(3,4,5-trimethoxyphenyl)magnesium3-[((5R,6S,7R,8R)-7-[[(triisopropylsilyl)oxy]methyl]-5-(3,4,5-trimethoxyphenyl)-8-[[2-(trimethylsilyl)ethoxy]methoxy]-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxol-6-yl)carbonyl]-1,3-oxazolidin-2-one(5R,5aS,8aR,9R)-5-(3,4,5-trimethoxyphenyl)-9-[[2-(trimethylsilyl)ethoxy]methoxy]-5,8,8a,9-tetrahydrofuro[3',4':6,7]naphtho[2,3-d][1,3]dioxol-6(5aH)-one(5R,5aR,8aR,9R)-5-(3,4,5-trimethoxyphenyl)-9-[[2-(trimethylsilyl)ethoxy]methoxy]-5,8,8a,9-tetrahydrofuro[3',4':6,7]naphtho[2,3-d][1,3]dioxol-6(5aH)-one5-(3,4,5-trimethoxyphenyl)-7H-[1,3]dioxolo[4,5-g]isochromen-7-one(5R)-5-[[(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl]oxy]-2(5H)-furanone(1R,11R,12R,13R,16R)-13-[[(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl]oxy]-1-(3,4,5-trimethoxyphenyl)-5,7,14,17-tetraoxapentacyclo[9.5.2.0(2,10).0(4,8).0(12,16)]octadeca-2(10),3,8-triene-15,18-dione(5R,5aR,6R)-6-[[(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl]oxy]-8-oxo-9-(3,4,5-trimethoxyphenyl)-5,5a,6,8-tetrahydrofuro[3',4':6,7]naphtho[2,3-d][1,3]dioxole-5-carboxylic acid(5R,5aR,6R,8aR,9R)-6-[[(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl]oxy]-8-oxo-9-(3,4,5-trimethoxyphenyl)-5,5a,6,8,8a,9-hexahydrofuro[3',4':6,7]naphtho[2,3-d][1,3]dioxole-5-carboxylic acid(5R,5aS,6R,8aR,9R)-6-[[(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl]oxy]-8-oxo-9-(3,4,5-trimethoxyphenyl)-5,5a,6,8,8a,9-hexahydrofuro[3',4':6,7]naphtho[2,3-d][1,3]dioxol-5-yl acetate(5R,5aR,8R,8aS)-8,9-dihydroxy-5-(3,4,5-trimethoxyphenyl)-5,8,8a,9-tetrahydrofuro[3',4':6,7]naphtho[2,3-d][1,3]dioxol-6(5aH)-onemethyl (5R,6R,7S)-7-formyl-8-hydroxy-5-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6-carboxylatemethyl (5R,6R,7R)-8-hydroxy-7-(hydroxymethyl)-5-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6-carboxylatemethyl (5R,6R,7R,8R)-8-hydroxy-7-(hydroxymethyl)-5-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6-carboxylateBenzyl chloromethyl ether; 1-[(chloromethoxy)methyl]benzeneethyl (5R,6R)-8-oxo-5-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6-carboxylateethyl (5R,6S)-8-oxo-5-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6-carboxylateethyl (5R,6R)-5-(3,4,5-trimethoxyphenyl)-8-[(trimethylsilyl)oxy]-5,6-dihydronaphtho[2,3-d][1,3]dioxole-6-carboxylateethyl (5R,6R,7R)-7-[(benzyloxy)methyl]-8-oxo-5-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6-carboxylate(1R,11R,12R,15R)-15-[(benzyloxy)methyl]-11-(3,4,5-trimethoxyphenyl)-5,7,14-trioxatetracyclo[10.2.1.0(2,10).0(4,8)]pentadeca-2(10),3,8-trien-13-one(1R,11R,12R,15R)-15-(hydroxymethyl)-11-(3,4,5-trimethoxyphenyl)-5,7,14-trioxatetracyclo[10.2.1.0(2,10).0(4,8)]pentadeca-2(10),3,8-trien-13-one2-Propen-1-ol; Allyl alcoholmethyl 7-methylnaphtho[2,3-d][1,3]dioxole-6-carboxylatemethyl 7-(bromomethyl)naphtho[2,3-d][1,3]dioxole-6-carboxylatemethyl 7-[(allyloxy)methyl]naphtho[2,3-d][1,3]dioxole-6-carboxylate(2S,3R)-3-amino-4-methoxy-2-butanol(4R,5R)-2-[7-[(allyloxy)methyl]naphtho[2,3-d][1,3]dioxol-6-yl]-4-(methoxymethyl)-5-methyl-4,5-dihydro-1,3-oxazole; allyl [7-[(4R,5R)-4-(methoxymethyl)-5-methyl-4,5-dihydro-1,3-oxazol-2-yl]naphtho[2,3-d][1,3]dioxol-6-yl]methyl ether[7-[(4R,5R)-4-(methoxymethyl)-5-methyl-4,5-dihydro-1,3-oxazol-2-yl]naphtho[2,3-d][1,3]dioxol-6-yl]methanol(4R,5R)-2-[7-([[tert-butyl(dimethyl)silyl]oxy]methyl)naphtho[2,3-d][1,3]dioxol-6-yl]-4-(methoxymethyl)-5-methyl-4,5-dihydro-1,3-oxazole; tert-butyl(dimethyl)silyl [7-[(4R,5R)-4-(methoxymethyl)-5-methyl-4,5-dihydro-1,3-oxazol-2-yl]naphtho[2,3-d][1,3]dioxol-6-yl]methyl ether(3,4,5-trimethoxyphenyl)lithium(4R,5R)-2-[(5R)-7-([[tert-butyl(dimethyl)silyl]oxy]methyl)-5-(3,4,5-trimethoxyphenyl)-5,6-dihydronaphtho[2,3-d][1,3]dioxol-6-yl]-4-(methoxymethyl)-5-methyl-4,5-dihydro-1,3-oxazole; tert-butyl(dimethyl)silyl [(8R)-7-[(4R,5R)-4-(methoxymethyl)-5-methyl-4,5-dihydro-1,3-oxazol-2-yl]-8-(3,4,5-trimethoxyphenyl)-7,8-dihydronaphtho[2,3-d][1,3]dioxol-6-yl]methyl ether(1R,2R)-2-(acetamido)-3-methoxy-1-methylpropyl (5R)-7-[(acetoxy)methyl]-5-(3,4,5-trimethoxyphenyl)-5,6-dihydronaphtho[2,3-d][1,3]dioxole-6-carboxylate(5R)-5-(3,4,5-trimethoxyphenyl)-5,9-dihydrofuro[3',4':6,7]naphtho[2,3-d][1,3]dioxol-6(8H)-onemethyl (5R,6S)-7-([[tert-butyl(dimethyl)silyl]oxy]methyl)-5-(3,4,5-trimethoxyphenyl)-5,6-dihydronaphtho[2,3-d][1,3]dioxole-6-carboxylatemethyl (5R,6R,7R)-7-bromo-7-([[tert-butyl(dimethyl)silyl]oxy]methyl)-8-hydroxy-5-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6-carboxylatemethyl (5R,6S,7S)-7-([[tert-butyl(dimethyl)silyl]oxy]methyl)-8-hydroxy-5-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6-carboxylatemethyl (5R,6S,7S)-7-([[tert-butyl(dimethyl)silyl]oxy]methyl)-8-hydroxy-5-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6-carboxylatemethyl (5R,6S,7S)-7-([[tert-butyl(dimethyl)silyl]oxy]methyl)-8-oxo-5-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6-carboxylate(5aS,8aS,9R)-5a-(hydroxymethyl)-9-(3,4,5-trimethoxyphenyl)-5a,6,8a,9-tetrahydrofuro[3',4':6,7]naphtho[2,3-d][1,3]dioxole-5,8-dione(5aR,8aS,9R)-9-(3,4,5-trimethoxyphenyl)-5a,6,8a,9-tetrahydrofuro[3',4':6,7]naphtho[2,3-d][1,3]dioxole-5,8-dione(5R,5aS,8aR,9R)-9-hydroxy-5-(3,4,5-trimethoxyphenyl)-5,8,8a,9-tetrahydrofuro[3',4':6,7]naphtho[2,3-d][1,3]dioxol-6(5aH)-one(5R,5aS,8aR,9R)-9-[[tert-butyl(dimethyl)silyl]oxy]-5-(3,4,5-trimethoxyphenyl)-5,8,8a,9-tetrahydrofuro[3',4':6,7]naphtho[2,3-d][1,3]dioxol-6(5aH)-one(5R,5aR,8aR,9R)-9-[[tert-butyl(dimethyl)silyl]oxy]-5-(3,4,5-trimethoxyphenyl)-5,8,8a,9-tetrahydrofuro[3',4':6,7]naphtho[2,3-d][1,3]dioxol-6(5aH)-one2-(Dimethylsulfonium)acetic acid ethyl ester inner saltdiethyl succinateethyl (5R,6R)-8-oxo-5-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6-carboxylate1,3-benzodioxol-5-yl(3,4,5-trimethoxyphenyl)methanone(E)-4-(1,3-benzodioxol-5-yl)-3-(ethoxycarbonyl)-4-(3,4,5-trimethoxyphenyl)-3-butenoic acid4-(1,3-benzodioxol-5-yl)-3-(ethoxycarbonyl)-4-(3,4,5-trimethoxyphenyl)butyric acidacetic 3-(1,3-benzodioxol-5-yl)-2-(ethoxycarbonyl)-3-(3,4,5-trimethoxyphenyl)butyric anhydridediethyl 2-[2-(1,3-benzodioxol-5-yl)ethyl]-2-(3,4,5-trimethoxybenzyl)malonatediethyl 5-(3,4,5-trimethoxyphenyl)-7,8-dihydronaphtho[2,3-d][1,3]dioxole-6,6(5H)-dicarboxylatediethyl 2-(3,4,5-trimethoxybenzylidene)malonate[6-(2-bromo-1-methoxyethyl)-1,3-benzodioxol-5-yl]lithiumdiethyl 8-methoxy-5-(3,4,5-trimethoxyphenyl)-7,8-dihydronaphtho[2,3-d][1,3]dioxole-6,6(5H)-dicarboxylate(E)-1-(1,3-benzodioxol-5-yl)-3-(3,4,5-trimethoxyphenyl)-2-propen-1-oneethyl 2-(1,3-benzodioxol-5-ylcarbonyl)-3-(3,4,5-trimethoxyphenyl)cyclopropanecarboxylate1,3-benzodioxole-5-carbonyl chlorideethyl (5R,6R)-8-oxo-5-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6-carboxylateethyl (E)-3-(3,4,5-trimethoxyphenyl)-2-propenoatepotassium 3-methoxy-3-oxopropanoate4-ethyl 3-methyl (3S,4R,5R)-2-oxo-5-(3,4,5-trimethoxyphenyl)tetrahydro-3,4-furandicarboxylate4-ethyl 3-methyl (3S,4R,5R)-3-(1,3-benzodioxol-5-ylcarbonyl)-2-oxo-5-(3,4,5-trimethoxyphenyl)tetrahydro-3,4-furandicarboxylateDimethyl acetylenedicarboxylate; Dimethyl 2-butynedioate;Acetylenedicarboxylic acid dimethyl ester[6-(dimethoxymethyl)-1,3-benzodioxol-5-yl](3,4,5-trimethoxyphenyl)methanol4-furo[3,4-f][1,3]benzodioxol-5-yl-2,6-dimethoxyphenyl methyl ether; 5-(3,4,5-trimethoxyphenyl)furo[3,4-f][1,3]benzodioxoledimethyl (1R,11S)-1-(3,4,5-trimethoxyphenyl)-5,7,14-trioxatetracyclo[9.2.1.0(2,10).0(4,8)]tetradeca-2(10),3,8,12-tetraene-12,13-dicarboxylatemethyl (1R,11R,12S,13R)-13-(hydroxymethyl)-11-(3,4,5-trimethoxyphenyl)-5,7,14-trioxatetracyclo[9.2.1.0(2,10).0(4,8)]tetradeca-2(10),3,8-triene-12-carboxylatemethyl (5R,6R,7R,8S)-8-hydroxy-7-(hydroxymethyl)-5-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6-carboxylate(5R,6R,7R,8R)-8-hydroxy-7-(hydroxymethyl)-5-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6-carboxylic aciddimethyl (Z)-2-butenedioate; Dimethyl Maleate5-(3,4,5-trimethoxyphenyl)-7H-[1,3]dioxolo[4,5-g]isochromen-7-onemethyl (5R,6R,7R,8R)-8-hydroxy-7-(hydroxymethyl)-5-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6-carboxylatemethyl (5R,6R,7R,8S)-8-hydroxy-7-(hydroxymethyl)-5-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6-carboxylatedimethyl (1S,11S,14R,15S)-13-oxo-11-(3,4,5-trimethoxyphenyl)-5,7,12-trioxatetracyclo[9.2.2.0(2,10).0(4,8)]pentadeca-2(10),3,8-triene-14,15-dicarboxylatedimethyl (5R,6R)-5-(3,4,5-trimethoxyphenyl)-5,6-dihydronaphtho[2,3-d][1,3]dioxole-6,7-dicarboxylatedimethyl (1R,11R,14S,15S)-13-oxo-11-(3,4,5-trimethoxyphenyl)-5,7,12-trioxatetracyclo[9.2.2.0(2,10).0(4,8)]pentadeca-2(10),3,8-triene-14,15-dicarboxylate(5R,6R,7R,8R)-6,7-bis(methoxycarbonyl)-8-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-5-carboxylic aciddimethyl (5S,6S,7R,8R)-5-(acetoxy)-8-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6,7-dicarboxylatedimethyl (E)-2-butenedioate(5R,6S)-6-(3,4,5-trimethoxyphenyl)-5,6-dihydrocyclobuta[f][1,3]benzodioxol-5-yl acetatemethyl (E)-4-isocyanato-2-butenoatemethyl (E)-4-[([[(5R,6S)-6-(3,4,5-trimethoxyphenyl)-5,6-dihydrocyclobuta[f][1,3]benzodioxol-5-yl]oxy]carbonyl)amino]-2-butenoate(4aR,5R,6R,11bR)-2-oxo-6-(3,4,5-trimethoxyphenyl)-3,4,4a,5,6,11b-hexahydro-2H-[1,3]dioxolo[4',5':6,7]naphtho[2,1-e][1,3]oxazine-5-carboxylic acid(5R,6R,7R,8R)-7-(aminomethyl)-8-hydroxy-5-(3,4,5-trimethoxyphenyl)-5,6,7,8-tetrahydronaphtho[2,3-d][1,3]dioxole-6-carboxylic acid
